Enzymatic Hydrolysis of meso(syn-syn)-1,3,5-Triacetoxy-2,4-dimethylpentane and Acetylation of meso(syn-syn)-3-Benzyloxy-2,4-dimethylpentane-1,5-diol by Lipase.
نویسندگان
چکیده
منابع مشابه
2,8-Dimethyltricyclo[5.3.1.13,9]dodecane-syn-2,syn-8-diol–propanoic acid (1/1)
The racemic title compound, C(14)H(24)O(2)·C(3)H(6)O(2), crystallizes in the monoclinic space group P2(1)/c as a 1:1 diol/carboxylic acid cocrystal, A-B. The lattice incorporates infinite chains of the alcohol-carboxylic acid-alcohol supra-molecular synthon, (⋯O-H⋯O=C(R)-O-H⋯O-H⋯), in which the hydrogen-bonded mol-ecules (A-B-A)(n) surround a pseudo-threefold screw axis. The carboxylic acid gro...
متن کاملDiastereomer-differentiating hydrolysis of 1,3-diol-acetonides: a simplified procedure for the separation of syn- and anti-1,3-diols.
[reaction: see text] A new method to facilitate the separation of diastereomeric syn- and anti-1,3-diols is described. The method relies on the different hydrolysis rates of the corresponding diastereomeric acetonides. Treatment of a dichloromethane solution of syn- and anti-1,3-diol-acetonide with a catalytic amount of diluted aqueous hydrochloric acid leads to the selective cleavage of the an...
متن کاملSYN-dog: Sniffing SYN Flooding Sources
This paper presents a simple and robust mechanism called SYN-dog to sniff SYN flooding sources. We install SYN-dog as a software agent at leaf routers that connect stub networks to the Internet. The statelessness and low computation overhead of SYN-dog make itself immune to any flooding attacks. The core mechanism of SYN-dog is based on the protocol behavior of TCP SYN—SYN/ACK pairs, and is an ...
متن کاملPlant Biotechnology 24, 135–147 (2007)
Tomato has been a good model plant to analyze plant-pathogen interactions and its prospects for the future are promising. An international consortium named International Solanaceae Genomics Project (SOL) is proceeding with whole genome sequencing of tomato. In order to be relevant in the post-genomic era, accumulation of information on tomatopathogen interactions is important. In this review, t...
متن کاملTCP SYN Flooding Defense
The TCP SYN ooding denial-of-service attack pointed out a weakness of then-current Internet protocols. There have since been many proposals to defend against SYN ooding, some requiring signiicant changes to TCP. Several solutions attempting to resolve the TCP weakness are now generally available. We document these existing solutions and qualitatively compare them. We reene the analysis of the r...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Chemical and Pharmaceutical Bulletin
سال: 1996
ISSN: 0009-2363,1347-5223
DOI: 10.1248/cpb.44.1391